| 摘要 |
<p>Phase-change type, reversible optical information recording medium, being possible for recording, reproducing, erasing, and rewriting of information, by use of a laser beam. This invention consists of recording thin film of ternary compositions, for example, containing Ge, Te, Sb /or Bi or quaternary compositions containing the fourth element of Se with which a part of Te is replaced, which is established on such surface -flat substrates as glass or plastics. In this case, the component ratio of Te and Se is selected not to be in excess for other elements, such as Ge, Sb /or Bi so as to be fixed as stable compounds of stoichiometric compositions of GeTe, Sb2Te3 /or Bi2Te3, or GeSe, Sb2Se3 /Bi2Se3 when crystallized. Strictly speaking, a concentration of each component is selected to have proper ratio of the number of atoms relative to each other so as to represent whole composition as the sum of each component. By this treatment, it is possible to have high crystallization speed and long cyclability of recording/erasing. The effect of Se is to increase the viscosity of the system and to make easily to obtain amorphous state; and moreover, by selecting of proper amount replaced with Te, it is possible to obtain the composition of recording film superior in both characteristics of recording (amorphization) and erasing (crystallization).</p> |
