IMPROVED OPERATION AND REGENERATION OF PERMSELECTIVE ION-EXCHANGE MEMBRANE IN BRINE ELECTROLYSIS CELLS

摘要

A method of operating and regenerating an electrolysis cell for electrolysing aqueous alkali metal halide solution and having permselective cation exchange membrane forming an anolyte and a catholyte compartment. The method comprises the steps of; feeding to and electrolyzing in said cell a brine which, at least prior to the brine's becoming part of the anolyte, contains no more than 5 ppm hardness (expressed as ppm calcium) and no more than 70 ppm carbon dioxide, carbonic acid, carbonate and bicarbonate (expressed as ppm CO2); regenerating the membrane by contacting the membrane on at least one of its sides with a solution capable of dissolving the multivalent cation compounds fouling the membrane for a time sufficient to dissolve a substantial amount of the compounds, the solution having a pH lower than the pH of the electrolyte which contacted that side of the membrane during the normal cell electrolysis.