发明名称 PREPARATION OF NOBLE METAL ORGANOSOL
摘要 PURPOSE:To efficiently convert a specific noble metal hydrosol to a noble metal organosol, by adding a nonionic surfactant to the specific noble metal hydrosol before or after the reducing treatment thereof to evaporate said hydrosol to dryness before adding an aprotic org. solvent thereto. CONSTITUTION:An aqueous solution containing a salt of a noble metal such as ruthenium, palladium and platinum is subjected to reducing treatment in the presence or absence of a protective agent to form a noble metal hydrosol and a nonionic surfactant is added to said hydrosol before and after the reducing treatment thereof to dissolve the same. Next, the resulting mixture is evaporated to dryness to remove water being a dispersing medium and an org. solvent is added to the dried one to again dissolve the same to prepare a noble metal organosol. In the reducing treatment of the noble metal, a reducing agent of an aqueous solution containing sodium borohydride or potassium borohydride is suitably used.
申请公布号 JPS61107937(A) 申请公布日期 1986.05.26
申请号 JP19840230729 申请日期 1984.11.01
申请人 AGENCY OF IND SCIENCE & TECHNOL 发明人 NAKAO YUKIMICHI;KAERIYAMA KYOJI;SUDA MASAO
分类号 C07C5/03;B01J13/00;B01J23/40;B22F9/24;C07B61/00;C07C1/00;C07C9/15;C07C67/00 主分类号 C07C5/03
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