发明名称 Process for the preparation of potassium sulphate, which can be used especially in fertilizers, from brines containing sulphate and potassium ions
摘要 New process for the treatment of brines containing, per litre, 16 to 85 g of magnesium, 3 to 15 g of potassium, 43 to 10 g of sodium, 1 to 0.5 g of calcium, 15 to 55 g of sulphate, 108 to 237 g of chloride, 1.7 to 1.6 g of bromide and 0.15 to 0.54 g of carbonate, characterised in that the following operations are carried out successively: 1. Maximum removal of sodium chloride by evaporation of the brine; 2. Cooling of the resulting preconcentrated brine to a temperature of between 15 and -10 DEG C, so as to crystallise epsomite; 3. Precipitation of non-sulphated carnallite and isolation of this carnallite; 4. Aqueous decomposition of the carnallite obtained for the purpose of obtaining a precipitate composed of KCl, and 5. Subsequent reaction, by any known process, of the epsomite and the KCl thus obtained, so as to prepare pure potassium sulphate. <IMAGE>
申请公布号 FR2573413(A1) 申请公布日期 1986.05.23
申请号 FR19850017189 申请日期 1985.11.20
申请人 ALSACE MINES POTASSE 发明人 MICHEL BODU, FREDERIC GUINIER ET KHALIFA BOUAZIZ
分类号 C01D3/08;C01D5/10;C01F5/00;(IPC1-7):C01D5/02;C05D1/02 主分类号 C01D3/08
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