发明名称 |
PROCESS FOR THE HYDROGENATION OF PERHALOGENATED TEREPHTHALONITRILES TO AMINES, 2,3,5,6-TETRAFLUOROXYLYLENE DIAMINE AND SALTS THEREOF |
摘要 |
A process for the hydrogenation of perhalogenated terephthalonitriles to their corresponding amines under acid conditions. The process is suitably conducted under a pressure of 1 to 100 atmospheres and at a temperature of from 0 to 200 DEG C in the presence of (i) a hydrogenation catalyst containing 0.1 to 70% by weight of a metal in Group 8 of the Periodic Table, (ii) an inorganic acid in an amount at least chemically equivalent to the amine formed and (iii) a solvent which is inert to the reaction ingredients and which does not poison the catalyst; the concentration of nitrile in the total reaction mixture being from 3 to 25% by weight. Preferably water is present in such amount that the proportion of water to solvent is from 1:50 to 1:1 parts by weight. The diamines obtained by this process are useful intermediates in the preparation of pesticidal compounds. 2,3,5,6-Tetrafluoroxylylene diamine and its salts are novel compounds. |
申请公布号 |
DE3361399(D1) |
申请公布日期 |
1986.01.16 |
申请号 |
DE19833361399 |
申请日期 |
1983.05.06 |
申请人 |
IMPERIAL CHEMICAL INDUSTRIES PLC |
发明人 |
RICHARDSON, PETER JOHN |
分类号 |
C07B61/00;B01J23/00;B01J23/40;C07C67/00;C07C209/00;C07C209/48;C07C211/29;(IPC1-7):C07C85/12;C07C87/28 |
主分类号 |
C07B61/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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