发明名称 PRODUCTION OF PHTHALIDE
摘要 PURPOSE:To produce the titled compound useful as a raw material for the production of pharmaceuticals, etc., nearly quantitatively, in high purity, without producing by-products, by carrying out the catalytic hydrogenation of phthalic anhydride in an inert solvent in the presence of a ruthenium complex catalyst at a temperature within a specific range. CONSTITUTION:The objective compound can be produced by the catalytic hydrogenation of phthalic anhydride in the presence of a ruthenium complex catalyst of formula (X is H, Cl, etc.; n is 0-2; when n is 2, plural Xs may be same or different; L is CO, etc.; y is 0-3; when y is 2 or 3, plural Ls may be same or different; R is 1-15C alkyl, etc.; x is 1-4), in an inert solvent at 160-210 deg.C. EFFECT:The objective compound can be separated and purified easily, and the process is extremely excellent from the industrial viewpoint.
申请公布号 JPS60215681(A) 申请公布日期 1985.10.29
申请号 JP19840070026 申请日期 1984.04.10
申请人 NIPPON SHOKUBAI KAGAKU KOGYO KK 发明人 KASHIWATANI KOUKICHI;TAKATANI NORIO;KUBOTA KUNITAKA
分类号 C07D307/88;B01J31/00;B01J31/24;C07B61/00 主分类号 C07D307/88
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