发明名称 PREPARATION OF 12-AMINODODECANOIC ACID
摘要 PURPOSE:To obtain the titled compound useful as a polyamide raw material, a curing agent for epoxy resin, an improver for polyester, etc., by hydrogenating a 11-cyanoundecanoic acid in the presence of a noble metal catalyst by addition of a specific chemical substance. CONSTITUTION:11-Cyanoundecanoic acid, its alkali metal salt, its ammonium salt, or its lower alkyl ester is hydrogenated in the presence of a noble metal catalyst by addition of a chemical compound (e.g., ethylenediaminetetraacetic acid, citric acid, condensed phosphate, etc.) having a multidentate ligand which is linked to a metallic ion to form a chelate compound, to give the desired compound. An amount of the chemical substance added is preferably 0.001-0.1, especially preferably 0.02-0.01pts.wt. based on 100pts.wt. feed solution (containing catalyst) to a hydrogenating reactor. EFFECT:A polymer obtained by polymerizing the final reaction product has high melt viscosity and no coloring even if it has the same relative viscosity.
申请公布号 JPS60163849(A) 申请公布日期 1985.08.26
申请号 JP19840017164 申请日期 1984.02.03
申请人 UBE KOSAN KK 发明人 YOSHIDA YUKIO;ASANO MASAYUKI;SUGISHITA HIDEYUKI;MATSUNISHI MASARU
分类号 C07B61/00;B01J23/00;B01J23/38;C07C67/00;C07C227/00;C07C227/04;C07C227/10;C07C229/08;C08G69/08 主分类号 C07B61/00
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