发明名称 PRODUCTION OF POLYPRENYL COMPOUND OR MIXTURE THEREOF
摘要 PURPOSE:To separate the titled substance useful as an intermediate for producing mammalian dolichol from an extract, by extracting a leaf of a plant belonging to the genus Keteleeria, Tsuga, Pseudotsuga or Larix of the family Pinaceae with an organic solvent, and obtaining the extract. CONSTITUTION:A leaf of a plant belonging to the genus Keteleeria, Tsuga, Pseudotsuga or Larix of the family Pinaceae is extracted with an organic solvent, e.g. a hydrocarbon, halogenated hydrocarbon, ether, or ester or ketone, and a polyprenyl compound of the formula (A is OH or acyloxy; n is an integer 12- 18) or a mixture thereof is obtained from the extract. The aimed substance is separated from the extract by subjecting the extract to the separation method, e.g. chromatography, fractional dissolution method, etc., and isolating a fraction exhibiting 0.18-0.25 or 0.50-0.55 Rf value under conditions as to give 0.40- 0.45 Rf value of solanesyl acetate using a thin layer chromatographic plate manufactured by Merck & Co., Inc. with a mixed solvent of n-hexane and ethyl acetate as a developing solvent.
申请公布号 JPS60109535(A) 申请公布日期 1985.06.15
申请号 JP19830215258 申请日期 1983.11.15
申请人 KURARAY KK 发明人 KINUHATA KOUICHI;TAKIGAWA TETSUO;OKADA MASAFUMI;MIZUNO MASAO;NISHIDA TAKUJI
分类号 C07C33/02;C07C27/00;C07C29/00;C07C67/00;C07C69/025 主分类号 C07C33/02
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