发明名称 |
Process for removing hydroperoxides and aldehydes from allyl-alkyl ether |
摘要 |
Described herein is a process for the conversion of hydroperoxides, present in allyl-alkyl ethers to products including alpha , beta -unsaturated aldehydes and for reducing such alpha , beta -unsaturated aldehydes to alcohols prior to the use of the ether as a feedstock in a hydroformylation reaction to produce the corresponding ether aldehyde. The process involves contacting the ether with a metal hydride, either in aqueous solution and/or by means of an ion exchange resin. Such treatment decomposes the hydroperoxides and then reduces their alpha , beta -unsaturated aldehyde decomposition products, thereby reducing the catalyst inhibition period present in the hydroformylation reaction which is observed when such alpha , beta -unsaturated aldehyde impurities are present.
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申请公布号 |
US4518805(A) |
申请公布日期 |
1985.05.21 |
申请号 |
US19830466023 |
申请日期 |
1983.02.14 |
申请人 |
UNION CARBIDE CORPORATION |
发明人 |
ABATJOGLOU, ANTHONY G.;BRYANT, DAVID R. |
分类号 |
C07C29/17;C07C31/10;C07C41/36;C07C41/44;C07C45/49;C07C45/53;(IPC1-7):C07C45/50 |
主分类号 |
C07C29/17 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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