发明名称 |
Process for recovering triarylphosphine from poisoned rhodium catalyst systems |
摘要 |
A process for recovering re-usable triarylphosphine (e.g. triphenylphosphine) from rhodium catalyst residues poisoned by the presence of alkyldiarylphosphine (e.g. n-propyldiphenylphosphine) such as are obtained as spent catalyst residues from the hydroformylation of olefins. The process comprises subjecting the poisoned residues to evaporative separation under reduced pressure to separate a vapor comprising triarylphosphine from the rhodium and then mixing the condensed vapor with polar solvent and obtaining the triarylphosphine as a crystalline precipitate from the solvent. The crystalline phosphine is sufficiently free of poisons to be re-usable as a catalyst component in a hydroformylation process. |
申请公布号 |
US4503255(A) |
申请公布日期 |
1985.03.05 |
申请号 |
US19820373176 |
申请日期 |
1982.04.29 |
申请人 |
JOHNSON MATTHEY PUBLIC LIMITED COMPANY |
发明人 |
BOOKER, DAVID F.;GROVE, DAVID E.;COTTERILL, PHILLIP J.;TYSON, ROBERT G. |
分类号 |
C07C45/50;B01J31/40;B01J38/00;C07C45/00;C07C67/00;C07F9/50;(IPC1-7):C07F9/50 |
主分类号 |
C07C45/50 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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