发明名称 ALKYLATION OF SIDE CHAIN OF AROMATIC HYDROCARBON
摘要 PURPOSE:In alkylating the side chain of an aromatic hydrocarbon compound containing H on a carbon at alpha-position of side chain with an olefin, to use a catalyst obtained by supporting Na and/or Na amide on a carrier consisting of K2O and Al3O2. CONSTITUTION:An aromatic compound (e.g., toluene) containing H on a carbon at alpha-position of side chain is reacted with an olefin (e.g., propylene) by the use of a catalyst obtained by supporting Na and/or Na amide on a carrier shown by the formula (x is 0.5-11), to give a side chain-alkylated aromatic hydrocarbon (e.g., isobutylbenzene). The carrier can support 0.1-20wt% calculated as Na atom of Na compound, and, since absorption and support are carried out extremely rapidly, the carrier has improved dispersion state, so the catalyst providing high activity and selectivity ratio can be formed. USE:A raw material for drugs, agricultural chemicals, and perfume.
申请公布号 JPS59222427(A) 申请公布日期 1984.12.14
申请号 JP19830096756 申请日期 1983.05.31
申请人 NIPPON SEKIYU KK 发明人 KUDOU MICHIO;MATSUNO MITSUO;IMAI HIROSUKE
分类号 B01J23/00;B01J23/04;B01J27/00;B01J27/24;B01J32/00;C07B61/00;C07C1/00;C07C2/72;C07C15/02;C07C67/00 主分类号 B01J23/00
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