Selective catalytic dealkylation of 1,4-dialkylbenzene.

摘要

A mixture of dialkylbenzenes (from the alkylation of benzenes) contains 1,2-, 1,3-and 1,4- isomers; to selectively dealkylate the 1,4-isomer (e.g. p-cymene) the (usually gaseous) mixture is contacted with a bed of a catalyst which is a crystalline zeolite having (a) a silica: alumina mol ratio of at least 12 (e.g. up to 500) and a constrained index (indicating the channel size in the crystal) of 1 to 12, the zeolite being modified with a metal or metalloid (e,g, MgO) and treated with a Li compound, e.g. the acetate, to replace the positive ions with Li<+>. …Reaction can be at 250 DEG to 600 DEG C for 0.1 to 60 seconds; an inert gaseous diluent can be present with the alkylbenzene. After reaction the catalyst is regenerated by heating. …There can thus be provided a fairly pure 1-3- dialkylbenzene.