发明名称 HETEROPOLY ACIDS AND THEIR PRODUCTION AND USE
摘要 A heteropoly-acid of the formula: H3+x(PMo12-xVxO40).nH2O wherein x and n are numbers satisfying respectively the equations: 0</=x</=3 and n</=6, and comprising phosphorus as the central atom and molybdenum or molybdenum and vanadium as the coordinating atoms, or its reduction-form product, which is in a cubic crystal structure having diffraction lines at lattice spacings (d) of at least 8.4, 6.8, 5.9, 4.8, 4.2 and 3.4 in the X-ray powder diffraction. The heteropoly-acid is useful as a catalyst, especially as a catalyst in the production of methacrylic acid by the gas-phase catalytic oxidation of methacrolein.
申请公布号 DE3261040(D1) 申请公布日期 1984.11.29
申请号 DE19823261040 申请日期 1982.04.23
申请人 SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 SCHIMIZU, SHINKICHI;ICHIHASHI, HIROSHI;NAGAI, KOICHI
分类号 C07C57/05;B01J27/00;B01J27/19;B01J27/199;C01B25/16;C01B25/24;C07C51/00;C07C51/25;C07C67/00;(IPC1-7):C01G39/00;B01J23/28 主分类号 C07C57/05
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