发明名称 METHOD FOR DIMERIZATION AND CODIMERIZATION OF LOWER MONOOLEFIN
摘要 <p>PURPOSE:To dimerize and codimerize the titled compound rapidly in high yield, by using a catalyst obtained by incorporating an organoaluminum halide with a specific polyol compound, and adding a nickel compound to the resultant catalyst precursor. CONSTITUTION:A lower monoolefin is dimerized and codimerized in the presence of a catalyst obtained by incorporating (A) an organoaluminum halide with (B) at least one polyol compound selected from fatty acids and cycloaliphatic and aromatic polyols, and adding (C) at least one nickel compound selected from organic acid salts, inorganic acid salts and complex compounds to the resultant catalyst precursor. Thus, the above-mentioned reaction is rapidly and stably carried out in a high conversion. The amount of the component (B) to be used is 2mol or less, preferably 0.01-1mol based on one mole component (A).</p>
申请公布号 JPS59210033(A) 申请公布日期 1984.11.28
申请号 JP19830084734 申请日期 1983.05.14
申请人 NISSAN KAGAKU KOGYO KK 发明人 YOSHIMURA MASAHITO;HOSHIYAMA HIROSHI;TAKAMATSU HIDEKI;KOBAYASHI HIROSHI;TAKIGAWA SHINICHIROU
分类号 C07C2/30;B01J31/00;B01J31/26;C07B61/00;C07C1/00;C07C2/32;C07C11/02;C07C67/00 主分类号 C07C2/30
代理机构 代理人
主权项
地址