摘要 |
The invention relates to a method of preparing beta alkaline alumina parts particularly for use as solid electrolytes in electric cells of the sodium-sulphur type. It consists in mixing alumina and an alkaline carbonate in predetermined quantities, heating the mixture, crushing after cooling, forming the parts, sintering them and, after said forming, but prior to sintering depositing a layer of a compound of said alkaline metal on the surface of the parts in contact with the atmosphere to create an atmosphere rich in sodium in the immediate vicinity of the parts during sintering for compensating any loss of the element which may occur from the parts and minimizing the loss of alkaline metal by diffusion towards the outside of the parts. |