OXIMATOHYDRIDOSILANES AND AMINOXYHYDRIDOSILANES

摘要

A process whereby silanes of the general formula HSi(NRRI)x(RII)3-x are reacted in the presence of a catalyst with oximes or hydroxylamines in the stoichiometry of approximately one equivalent of oxime or hydroxylamine per mole of silicon-nitrogen linkage to give unexpectedly high yields of substituted silanes.