| 摘要 |
Method of carrying out cationic polymerization with molecular weight control in which a preinitiator precursor, e.g. a diol and a catalyst effective for cationic polymerization (or a preformed adduct of such precursor and catalyst) are mixed with a monomer (e.g. a cyclic ether) in proportions of one mol of precursor or adduct and n mols of monomer, where n is the relatively small number of mer units desired in the polymer, causing polymerization to proceed to completion, then treating the resulting living cationic polymer as desired, e.g. quenching with water to introduce a terminal hydroxyl group, adding another monomer to produce a block polymer, reacting with an anionic polymer, etc. Also polymers so formed. Such polymers have low polydispersity and conversion and yield of the desired polymer are high.
|
