Producing oximinosilanes, oximinogermanes and oximinostannanes.

摘要

A Group IVa metal halide such as methyl trichlorosilane is reacted with an oxime compound such as methyl ethyl ketone oxime in the absence of a base to form in high yields a product oximinosilane, oximinogermane or oximinostan- nane (e.g. methyl tris(methyl ethyl ketoximo) silane) and a by-product oxime hydrohalide. The oxime above that found in the product may be recovered by neutralization of the by-product oxime hydrohalide.