发明名称 Process for the production of carbinol bases from indoline compounds
摘要 The invention describes a novel single step process for the production of carbinol bases of the formula I <IMAGE> (I) wherein R is the methyl or ethyl group, each R3 independently is a C1-C4 alkyl group and the benzene rings A and/or B can be unsubstituted or substituted, which process comprises alkylating 1 mole of a dye base of the formula II <IMAGE> (II) or the hydrogen salt thereof of the formula IIa <IMAGE> (IIa) wherein R3, A and B are as defined for formula I and X is any anion, in aqueous alkaline medium having a pH value of at least 10, with at least 2 moles of a compound that introduces the radical R. The carbinol bases obtained are valuable intermediates for obtaining in particular cationic compounds containing any anions, especially carboxylic acid anions, most preferably an acetate anion.
申请公布号 US4372886(A) 申请公布日期 1983.02.08
申请号 US19810268956 申请日期 1981.06.01
申请人 CIBA-GEIGY CORPORATION 发明人 ZINK, RUDOLF;LOEW, PETER
分类号 C07D209/34;C09B26/02;C09B26/04;(IPC1-7):C09B55/00;C07D211/72 主分类号 C07D209/34
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