发明名称 2,2-DIMETHYL-3-(2-BROMO-2-PHENYL-VINYL)-CYCLOPROPANE CARBOXYLIC ACID 3-PHENOXY-BENZOYL ESTERS THEIR SYNTHESIS AND PESTICIDAL USE
摘要 2,2-Dimethyl-3-(2-bromo-2-phenyl-vinyl)-cyclopropanecarboxylic acid 3-phenoxybenzyl ester of the formula <IMAGE> which possess arthropodicidal properties. In addition, the new intermediate of the formula <IMAGE> is produced by reacting an alpha -bromo-benzyl-phosphonic acid ester of the formula <IMAGE> in which R6 each independently is alkyl or phenyl, or the two radicals R6 together are alkanediyl, with a 3-formyl-2,2-dimethyl-cyclopropanecarboxylic acid ester and saponifying. Also the compounds of the formula <IMAGE> which are new when R1 is not alkyl, are produced by reacting triphenylphosphine and bromine to form dibromo-triphenylphosphorane, and reacting the dibromo-triphenylphosphorane without isolation with an alpha -hydroxy-benzyl-phosphonic acid ester of the formula <IMAGE>
申请公布号 PH15309(A) 申请公布日期 1982.11.18
申请号 PH19700000230 申请日期 1979.09.26
申请人 BAYER AG 发明人 FUCHS RAINER;HOFFMANN HELLMUT;HAMMANN INGEBORG;HOMEYER BERNHARD;STENDEL WILHELM
分类号 C07C69/747;A01N53/00;A01N53/08;A01P7/02;A01P7/04;B01J27/00;B01J27/232;B01J31/00;C07C61/40;C07C67/00;C07C67/08;C07C67/14;C07C253/00;C07C255/39;C07C313/00;C07C323/62;C07D317/52;C07D317/62;C07F9/40 主分类号 C07C69/747
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