发明名称 PREPARATION OF METHYL AND ETHYL ESTERS
摘要 A process for the manufacture of a compound having the following general formula: (I) (wherein each of R1 and R2 is independently an alkyl group of 1 to 4 carbon atoms or R1 and R2 together represent an alkylene group of up to 5 carbon atoms; each of X1 and X2 is independently a hydrogen atom, an alkyl group of 1 to 4 carbon atoms, a halogen atom, or X1 and X2 together represent an alkylene group of up to 5 carbon atoms; or X1 is a hydrogen atom and X2 is monohalovinyl group, a dihalovinyl group or a dimethylvinyl group; and R is a methyl or ethyl group) which comprises reacting a cyclopropane nitrile having the general formula: (II) with methanol or ethanol under substantially anhydrous conditions at a temperature in the range 80.degree. to 200.degree.C and in the presence of sulphuric acid acting as reaction catalyst and as scavenger for ammonia produced during the reaction.
申请公布号 CA1123004(A) 申请公布日期 1982.05.04
申请号 CA19780306002 申请日期 1978.06.22
申请人 SHELL CANADA LIMITED 发明人 SYRIER, JOHANNES L.M.
分类号 C07C69/74;A01N;A01N53/10;B01J27/00;B01J27/02;C07B61/00;C07C;C07C67/22;C07C69/743 主分类号 C07C69/74
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