| 摘要 |
A process for the preparation of pure optically active tertiary phosphines by resolving the corresponding racemic compounds, wherein the phosphines are first converted to the corresponding phosphine oxides in a conventional manner, the resulting racemic mixtures of the phosphine oxides are reacted in organic solution, in accordance with the principles of enantiomer separation via stereomeric compounds, with an optically pure isomer of a tartaric acid which is mono-acylated or bis-acylated at the alcoholic hydroxyls, the diastereomeric compound which is less soluble in the solvent is separated off, the tartaric acid derivative is split off from the resulting pure diastereomeric compound by means of a base and the resulting optically pure or substantially optically pure phosphine oxides are reduced back to the phosphines in a conventional manner. The optically active tertiary phosphines may be used as ligands in complex compounds of metals of group VIII of the periodic table, and when such complexes are used as hydrogenating or hydroformylating catalysts they result in substantially stereospecific hydrogenation or hydroformylation of prochiral compounds.
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