发明名称 |
PROCESS FOR PRODUCING PROPYLENE-ETHYLENE BLOCK COPOLYMER |
摘要 |
A propylene-ethylene block copolymer is produced in the presence of a catalytic system essentially comprising an organoaluminum compound and a solid titanium trichloride catalytic complex having an atomic ratio of Al to Ti of less than 0.15 and having a complexing agent in two stages of polymerization; (a) a first stage for polymerizing propylene in the presence of a liquid propylene and hydrogen to produce a propylene homopolymer having a melt flow index of 1 to 150 at a ratio of 70 to 95% by weight based on a total of polymers; and (b) a second stage for copolymerizing propylene and ethylene in the presence of hydrogen and a liquid propylene at a concentration of propylene in vapor phase based on a total of propylene and ethylene in vapor phase of 50 to 85 mol. % and at a concentration of hydrogen in vapor phase based on a total of propylene and ethylene in vapor phase of 0.5 to 30 mol %, to produce ethylene-propylene copolymer having a melt flow index of 10-7 to 0.1 at a ratio of 5 to 30% by weight based on a total of polymers. |
申请公布号 |
AU6197880(A) |
申请公布日期 |
1981.04.30 |
申请号 |
AU19800061978 |
申请日期 |
1980.09.03 |
申请人 |
MITSUBISHI CHEMICAL INDUSTRIES LTD. |
发明人 |
M. HASUO ET AL |
分类号 |
C08F297/00;C08F4/64;C08F297/08 |
主分类号 |
C08F297/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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