发明名称 Acidic mixed oxide catalytic de-alkylation of tertiary-alkyl-ether-alkanols
摘要 A de-alkylation process which comprises contacting a t-alkylether-alkanol, e.g. 4-t-butylether-n-butan-1-ol, with an acidic solid mixed oxide, e.g. silica-alumina, catalyst which results in the formation of alkanediols, e.g. 1,4-butanediol, in the substantial absence of undesirable side reactions, e.g. the formation of tetrahydrofuran. The resulting alkanediols are useful in the preparation of polyesters, e.g. polybutylene terephthalates.
申请公布号 US4254290(A) 申请公布日期 1981.03.03
申请号 US19790105577 申请日期 1979.12.20
申请人 GENERAL ELECTRIC COMPANY 发明人 CHAMBERS, GREGORY R.;SMITH, WILLIAM E.
分类号 C07C29/10;C07D307/08;(IPC1-7):C07C31/18 主分类号 C07C29/10
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