Polymeric materials, process for preparing them and shaped articles and contact lenses formed from them.

摘要

Polymeric materials suitable for bio-medical applications, particularly in making contact lenses, are derived by reaction of the following monomers in the given proportions: (1) 20 to 40 mole % of a polymerisable amide which is an unsubstituted or substituted amide of a carboxylic acid containing olefinic unsaturation. (2) 25 to 55 mole % of an N-vinyl lactam, (3) 5 to 20 mole % of a polymerisable ester which is an ester of a carboxylic acid containing olefinic unsaturation. (4) 1 to 10 mole % of a polymerisable carboxylic acid containing olefinic unsaturation, (5) 3 to 10 mole % of a polymerisable hydrophobic vinyl monomer, the amounts of the monomers (1) to (5) totalling 100 mole % and the copolymer being crosslinked with a crosslinking agent. The polymeric materials of the invention may be machined to form contact lenses and subsequently hydrated to form a hydrogel which is suitable for use as an extended wear contact lens.