| 摘要 |
The present invention relates to a method for preparation of ion exchangers from hydrophilic anion-exchanging gels based on acrylate or methacrylate copolymers prepared by copolymerization of amino-group-containing monomers, selected from a group comprising aminoalkyl acrylates and methacrylates, aminoalkylacrylamides and aminoalkylmethacrylamides or on gels prepared by chemical bonding of amine groups to the hydrophylic matrix of acrylate or methacrylate copolymers. The method consists in alkylation or hydroxyalkylation of amine groups by alkylating agents, as alkyl halogenides, alkyl p-toluenesul-fonates, alkylsulfates and epoxides. Alkylation with alkyldiazo compounds was used for transformation of the undesired carboxylic groups of the ion exchangers. Another modification consists in the reaction of halogenated acrylate or methacrylate gels with polyamines or oligomeric polyethylene imines. These reactions lead to ion exchangers with modified chemical nature, dissociation constant, exchange capacity, degree of hydrophility, distance of the ionogenous groups from the surface of the matrix or the character of microsurroundings. The resulting ion-exchan-ging materials are suitable above all for the sorption and separation of biopolymers. |
