发明名称 |
Stoichiometric titanium disulphide prodn. - by heating titanium under a sulphur partial pressure |
摘要 |
<p>Stoichiometric TiS2 having a low crystal aspect ratio is obtd by heating particulate Ti to 475 degrees-600 degrees C in a atmos. having a S partial pressure equal to equilbrium S partial pressure over TiS2 at reaction temp. Amts. of Ti and S used are stoichiometric and temp. is held for sufficient time to homogenise TiS2. Ti is pref. sponge of particle size 100%-4 mesh to 100% + 40 mesh. Pref. reaction is carried out in an elongated vessel contg. a hot zone for the Ti and a cool zone in which S can condense. Hot zone temp. is 500-550 degrees C and cool zone is 50-300 degrees C lower. This enables S partial pressure to be controlled. Prod. is useful as cathode material in secondary batteries. By avoiding temps. >600 degrees C method yields a prod. having desirable crystal and size properties.</p> |
申请公布号 |
FR2371384(A1) |
申请公布日期 |
1978.06.16 |
申请号 |
FR19760035103 |
申请日期 |
1976.11.22 |
申请人 |
EXXON RESEARCH ENGINEERING CY |
发明人 |
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分类号 |
C01G23/00;H01M4/58;H01M10/052;H01M10/36;(IPC1-7):01G23/00;01M4/36 |
主分类号 |
C01G23/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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