发明名称 |
Carbon dioxide elimination from formyloxyalkynes - to give alkynyl esters,alkynes and allenes |
摘要 |
is split off from a cpd. of formula: R4CH(OCHO)-C triple bond C-CR1R2R3 (where R1 is H, 1-6C alkyl or OCOR5; R2-R5 are H or 1-6C alkyl; and when R1 = OCOR5, R2 = H) by contacting at 140-260 degrees C with a finely-divided gp. Ib metal (pref. Cu) and/or Cd or Zn and/or Ni, Pd or Pb or Pt or a cpd. of these metals which liberate the free metal under the reaction conditions. The prodts. are alkynyl formates, alkynyl alkanoates, alkynes and the corresp. isomeric allenes. The prodts. are intermediates, e.g. for insecticides, acaricides, corrosion inhibitors, vitamin E and plant growth promoters. |
申请公布号 |
DE2060083(A1) |
申请公布日期 |
1972.06.15 |
申请号 |
DE19702060083 |
申请日期 |
1970.12.07 |
申请人 |
BADISCHE ANILIN- & SODA-FABRIK AG |
发明人 |
HIMMELE,WALTER,DR.;FLIEGE,WERNER,DR.;FROEHLICH,HELMUT,DR. |
分类号 |
C07C1/213;C07C69/07 |
主分类号 |
C07C1/213 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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