发明名称 |
Integrated process for the preparation of 2-dialkoxyphosphinylimino-1,3-dithietane |
摘要 |
There is provided a fully integrated process for preparing a 2-dialkoxyphosphinylimino-1,3-dithietane in good overall yields with considerable savings in materials, time and labor involving a plurality of steps comprising the overall reaction of a dialkoxyphosphoryl chloride and an alkali metal- or ammonium thiocyanate to obtain a dialkoxyphosphinyl isothiocyanate, reacting the latter with 1.1 to 1.2 molar equivalents of an alkali mercaptan in the presence of a water and, finally, reacting resultant dialkoxyphosphinyldithiocarbamate with methylene bromide or methylene iodide in the presence or absence of a non-ionic surfactant under controlled pH conditions ranging from 5 to 8 to obtain resultant 2-dialkoxyphosphinylimino-1,3-dithietane. The latter finds utility for the control of root-knot nematode.
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申请公布号 |
US4065466(A) |
申请公布日期 |
1977.12.27 |
申请号 |
US19760695667 |
申请日期 |
1976.06.14 |
申请人 |
AMERICAN CYANAMID COMPANY |
发明人 |
REGER, DAVID WILLIAM;GARBER, MURRAY;LONG, DON WESLEY |
分类号 |
C07F9/24;C07F9/6553;(IPC1-7):C07D339/00 |
主分类号 |
C07F9/24 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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