发明名称 Fluorination process
摘要 Aromatic compounds containing an alpha -fluoroalkyl or alpha , alpha -difluoroalkyl side chain are prepared by reacting selected aromatic compounds with a mixture of HF and a metal oxide which is PbO2 or NiO2 at -30 DEG to +80 DEG C. Exemplary is the conversion of 4-nitrotoluene to 4-(fluoromethyl)nitrobenzene and 4-(difluoromethyl)nitrobenzene.
申请公布号 US4051168(A) 申请公布日期 1977.09.27
申请号 US19760685805 申请日期 1976.05.12
申请人 E. I. DU PONT DE NEMOURS AND COMPANY 发明人 FEIRING, ANDREW EDWARD
分类号 C07B39/00;C07C17/14;C07C22/08;C07C45/63;C07C47/55;C07C49/80;C07C49/813;C07C50/24;C07C63/70;C07C201/12;C07C205/11;C07C205/58;C07C309/28;C07C309/73;(IPC1-7):C07C143/24 主分类号 C07B39/00
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