发明名称 |
Fluorination process |
摘要 |
Aromatic compounds containing an alpha -fluoroalkyl or alpha , alpha -difluoroalkyl side chain are prepared by reacting selected aromatic compounds with a mixture of HF and a metal oxide which is PbO2 or NiO2 at -30 DEG to +80 DEG C. Exemplary is the conversion of 4-nitrotoluene to 4-(fluoromethyl)nitrobenzene and 4-(difluoromethyl)nitrobenzene.
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申请公布号 |
US4051168(A) |
申请公布日期 |
1977.09.27 |
申请号 |
US19760685805 |
申请日期 |
1976.05.12 |
申请人 |
E. I. DU PONT DE NEMOURS AND COMPANY |
发明人 |
FEIRING, ANDREW EDWARD |
分类号 |
C07B39/00;C07C17/14;C07C22/08;C07C45/63;C07C47/55;C07C49/80;C07C49/813;C07C50/24;C07C63/70;C07C201/12;C07C205/11;C07C205/58;C07C309/28;C07C309/73;(IPC1-7):C07C143/24 |
主分类号 |
C07B39/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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