摘要 |
1518636 Ammoxidation catalyst PRODUITS CHIMIQUES UGINE KUHLMANN 10 Feb 1977 [24 Feb 1976] 05565/77 Heading B1E [Also in Division C2] A catalyst for the preparation of an unsaturated nitrile by ammoxidation of an olefine comprises antimony, tin, tungsten, copper, tellurium and oxygen. The catalyst may have the empirical formula Sb 1-10 Sn 1-10 W 0À01-5 Cu 0À01-5 Te 0À01-5 O x . The catalyst may be prepared by dispersing antimony trioxide in aqueous nitric acid, adding powdered tin, washing, adding copper nitrate and tungsten trioxide, precipitating copper as hydroxide with ammonia, mixing tellurium oxide in the precipitate, pelleting or extrusion and heat treatment in air. |