| 发明名称 | Surface-modified cyanide-based transition metal compounds | ||
| 摘要 | A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition. The composition, compound, device, and uses thereof according to AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che)rq]z. (Che)rw(Vac)(1-z).nH2O (wherein Vac is a Mn(CN)(6-p-q)(NC)p(Che)rq vacancy); wherein Che is an acid chelating agent; wherein: A=Na, K, Li; and M=Mg, Al, Ca, Sc, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, Ga, Pd, Ag, Cd, In, Sn, Pb; and wherein 0<j≦4; 0≦k≦0.1; 0≦(p+q)<6; 0<x≦4; 0≦y≦1; 0<z≦1; 0<w≦0.2; 0<n≦6; −3≦r≦3; and wherein: x+2(y−k)+jk+(m+(r+1)q−6)z+wr=0. | ||
| 申请公布号 | US9359219(B1) | 申请公布日期 | 2016.06.07 |
| 申请号 | US201514880010 | 申请日期 | 2015.10.09 |
| 申请人 | Alveo Energy, Inc. | 发明人 | Motallebi Shahrokh;Wessells Colin Deane;Valencia Christian |
| 分类号 | C01C3/11;C01C3/12 | 主分类号 | C01C3/11 |
| 代理机构 | Patent Law Offices Michael E. Woods | 代理人 | Patent Law Offices Michael E. Woods ;Woods Michael E. |
| 主权项 | 1. A method for manufacturing an environment-stabilized transition metal cyanide coordination compound (TMCCC) material, comprising: a) producing a particulated TMCCC material; and thereafter b) combining the particulated TMCCC material with a solution including a material containing an acid group to produce a stabilized TMCCC material; wherein said stabilized TMCCC material includes: at least one composition represented by Formula I: AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che)rq]z.(Che)rw(Vac)(1-z).nH2O (Formula I) wherein, in Formula I, each A is an independently selected alkali metal Li, Na, or K; and each dopant M may optionally be at least one independently selected alkaline earth metal Mg or Ca, post-transition metal Al, Ga, In, Sn, or Pb, or transition metal Sc, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, Pd, Ag, or Cd having an average valence j; and Che represents an acid chelating agent which includes ligand binding atoms that form one or more covalent linkages with Mn or with Mn and M; and wherein 0<j≦4, 0≦k≦0.1, 0≦(p+q)≦6, 0<x≦4, 0<y≦1, 0<z≦1, 0<w≦0.2; −3≦r≦3; and 0≦n≦6; wherein x+2(y−k)+jk+(m+(r+1)q−6)z+wr=0; and wherein Formula I includes one or more Mn(CN)(6-p-q)(NC)p(Che)rq complexes each including an Mn atom, and wherein p is an average number of NC groups found in said one or more Mn(CN)(6-p-q)(NC)p(Che)rq complexes; and wherein q is an average number of Che groups found in said one or more Mn(CN)(6-p-q)(NC)p(Che)rq complexes; and wherein m is an average valence of said Mn atoms found in said one or more Mn(CN)(6-p-q)(NC)p(Che)rq complexes; wherein (Vac) identifies a Mn(CN)(6-p-q)(NC)p(Che)rq vacancy wherein CN identifies a cyano group; and wherein NC identifies an isocyano group. | ||
| 地址 | Palo Alto CA US | ||