发明名称 PRODUCTION OF TRIORGANOSILANOL
摘要 PROBLEM TO BE SOLVED: To provide a method of efficiently and inexpensively producing triorganosilanol by subjecting a triorganohydrogen silane to react with water in the presence of an inexpensive and homogeneous ruthenium catalyst which has carbonyl groups as ligands and can achieve high activity. SOLUTION: A triorganohydrogensilane represented by the following general formula (1) R1R2R3SiH (1) (wherein R1, R2 and R3 are mutually identical or different and means each a 1-10C unsubstituted or substituted monovalent hydrocarbon group) is characteristically allowed to react with water in the presence of a ruthenium catalyst bearing a carbonyl group as a ligand whereby the objective triorganosilanol is obtained that is represented by the following general formula (2) R1R2R3SiOH (2) (wherein R1, R2 and R3 each same as stated above).
申请公布号 JP2002020390(A) 申请公布日期 2002.01.23
申请号 JP20000208071 申请日期 2000.07.10
申请人 SHIN ETSU CHEM CO LTD 发明人 KUBOTA TORU;FUNATSU AKIYUKI;ENDO MIKIO;TONOMURA YOICHI
分类号 B01J31/20;C07B61/00;C07F7/08 主分类号 B01J31/20
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