发明名称 |
MONONUCLEAR IRON COMPLEX AND ORGANIC SYNTHESIS REACTION USING SAME |
摘要 |
Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound.
In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4. |
申请公布号 |
EP2963047(A4) |
申请公布日期 |
2016.08.24 |
申请号 |
EP20140757365 |
申请日期 |
2014.02.26 |
申请人 |
KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION;SHIN-ETSU CHEMICAL CO., LTD. |
发明人 |
NAGASHIMA, HIDEO;SUNADA, YUSUKE;TSUTSUMI, HIRONORI;HASHIMOTO, TORU;SAKUTA, KOJI |
分类号 |
C07F19/00;B01J31/22;C07C5/03;C07C9/16;C07C13/10;C07C13/18;C07C15/073;C07C15/18;C07C29/14;C07C29/143;C07C29/147;C07C31/135;C07C33/20;C07C41/26;C07C43/23;C07C209/50;C07C211/27;C07C211/29;C07C213/00;C07C217/58 |
主分类号 |
C07F19/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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