发明名称 PRODUCTION OF ALKENYLSUCCINIC ANHYDRIDE
摘要 PURPOSE:To obtain advantageously the titled compound useful as a sizing agent for paper making, by using an olefin containing >=60wt% specific olefin having 12-22 carbon atoms as a raw material, and isomerizing the olefin in the presence of a solid acid-base catalyst. CONSTITUTION:An olefin having 12-22 carbon atoms, shown by the formula (Rx is H, or 1-4C alkyl; Ry is straight-chain alkyl), comprising <=20mol% hydrogen component of Rx and >=60mol% component having 9-19 total carbon atoms of Rx and Ry, is used as a raw material, 0.5-1.5mol maleic anhydride is added to 1mol olefin of the raw material in the presence of a solid acid-base catalyst, and addition reaction is carried out under heating, preferably at 160-250 deg.C, to give the aimed compound. Silica titania, silica alumina, etc., having various composition ratios are used as the solid acid-base catalyst. An amount of it used is preferably 0.01-10wt% based on the raw material.
申请公布号 JPS61151182(A) 申请公布日期 1986.07.09
申请号 JP19840272187 申请日期 1984.12.24
申请人 MITSUBISHI MONSANTO CHEM CO 发明人 FUJINO SEIJI;TATSUOKA KENGO;INAGAKI YOICHI;NAGIRA KAZUHIKO
分类号 C07D307/60 主分类号 C07D307/60
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