发明名称 POLYMER-SUPPORTED ARYLBIS(PERFLUOROALKYLSULFONYL)-METHANE
摘要 <p>The present invention provides a solid acid catalyst that is excellent from the point of toxicity, environment and others, wherein reaction can be progressed effectively with Bronsted acid or Lewis acid catalyst. For example, the benzoylation reaction of alcohol can also be progressed easily, and further, the catalyst can be recovered and recycled easily. The para position of arylbis(perfluoroalkylsulfonyl)methane represented by the general formula Ä1Ü (wherein R<1> shows a substituted or unsubstituted aryl group, Rf<1> and Rf<2> are independent to each other and show a perfluoroalkyl group), a pentafluorophenylbis(perfluoroalkylsulfonyl)methane, for example, is supported on a polystyrene resin, and a polystyrene-supported arylbis(perfluoroalkylsulfonyl)methane represented by the general formula Ä3Ü (wherein R<3> shows a substituted or unsubstituted arylene group, Rf<1> and Rf<2> are the same as described above) is obtained. (Chemical formula 1) <CHEM> (Chemical formula 2) <CHEM></p>
申请公布号 EP1375532(A1) 申请公布日期 2004.01.02
申请号 EP20020702913 申请日期 2002.03.12
申请人 JAPAN SCIENCE AND TECHNOLOGY CORPORATION 发明人 ISHIHARA, KAZUAKI;YAMAMOTO, HISASHI
分类号 B01J31/02;B01J31/06;B01J31/10;C07B61/00;C07C17/14;C07C17/26;C07C29/38;C07C29/44;C07C33/30;C07C41/50;C07C41/56;C07C43/303;C07C45/51;C07C45/64;C07C45/67;C07C45/72;C07C49/83;C07C67/08;C07C69/78;C07C313/04;C08F8/34;(IPC1-7):C08F8/00;C07C45/69;B01J31/08 主分类号 B01J31/02
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