| 摘要 |
A process and device are disclosed for reducing the substance and energy losses due to leakages in the sealing area of the electrodes (2; 3) and the electrolyte (1) of electrochemical cells. While dispensing as much as possible with a total sealing, the reactants oxygen carrier and fuel which flow out of the electrode chambers in a perpendicular direction to the electric field intensity are forced in the marginal areas (10) of the bipolar plates (6; 7) to entertain and to complete as much as possible the reactions which are orderly carried out in the area of the field intensity. The energy conversion that results in the leakage spot increases the total electrochemical efficiency. The width of the marginal area (10) matches the thickness of the leakage spot (distance between the bipolar plates) in such a way that all reactions are concluded before the edge (9) is reached and only energy-free leakage currents (17; 18) leave the cell. The invention is suitable for cells of the ZrO2 electrolyte, cation exchange membrane, H3PO4, Li2/K2CO3, and KOH types. |
