发明名称 SOLID TITANIUM CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION, POLYMERIZATION METHOD OF OLEFIN
摘要 PROBLEM TO BE SOLVED: To obtain a catalyst component which has a high polymerization activity and gives a polymer having an excellent stereoregularity and a wide distribution of the molecular weight by blending, magnesium, titanium, a halogen, and a polycarboxylic acid ester as its essential components. SOLUTION: A polycarboxylic acid ester of the formula is used. In the formula, Z is a hydrocarbon; n is 1-7; and R1 and R2 are each a 1-20C hydrocarbon different from each other. A catalyst component is obtained by blending a magnesium compound, a titanium compound and the multivalent carboxylic acid ester. As the titanium compound, a compound of Ti(OR)nX4-n (wherein R is a hydrocarbon; X is a halogen; and 0<=n<=4) can be mentioned. The magnesium compound, preferably, does not have a reducing property and further preferably contains a halogen. For the polycarboxylic acid ester, Z is preferably an aromatic hydrocarbon group. This catalyst component is used with an organic metal compound catalyst component.
申请公布号 JP2000344818(A) 申请公布日期 2000.12.12
申请号 JP19990158519 申请日期 1999.06.04
申请人 MITSUI CHEMICALS INC 发明人 HAMA SHUNICHI;KANEKO HIDEYUKI;DOI YOSHIKO;KOJO SHINICHI
分类号 C08F10/00;C08F4/654;(IPC1-7):C08F4/654 主分类号 C08F10/00
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