发明名称 |
PRODUCTION METHOD FOR CHLORINATED VINYL CHLORIDE RESIN |
摘要 |
The present invention provides a method for producing a chlorinated polyvinyl chloride which is excellent in thermal stability (initial discoloration resistance, heat-resistant stability) and is capable of providing a transparent article. The present invention relates to a method for producing a chlorinated polyvinyl chloride through thermal chlorination of a reaction solution including a vinyl chloride aqueous suspension that contains a vinyl chloride resin in a hermetically sealable reaction vessel, the method including: step 1 of initiating thermal chlorination by heating the reaction solution to 55°C to 70°C and then introducing chlorine into the reaction vessel; step 2 of raising the temperature of the reaction solution while maintaining the temperature inside the reaction vessel not higher than the glass transition temperature of a partially chlorinated polyvinyl chloride; and step 3 of carrying out the thermal chlorination at a predetermined temperature of 85°C or higher but lower than 115°C after the chlorine content of the partially chlorinated polyvinyl chloride reaches 58% by weight or more, the steps 1 to 3 being performed under stirring at a net stirring power (Pv) inside the reaction vessel of 0.2 to 2.5 kw/m 3 per 1 m 3 of the reaction solution. |
申请公布号 |
EP3127926(A1) |
申请公布日期 |
2017.02.08 |
申请号 |
EP20150773847 |
申请日期 |
2015.03.31 |
申请人 |
Sekisui Chemical Co., Ltd.;Tokuyama Sekisui Co., Ltd. |
发明人 |
MATSUMURA Kenichi;MASHINO Norikazu |
分类号 |
C08F8/22;C08F14/06 |
主分类号 |
C08F8/22 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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