发明名称 METHOD FOR PRODUCING N-SUBSTITUTED (METH)ACRYLIC AMIDE
摘要 PROBLEM TO BE SOLVED: To provide a method for simply and inexpensively producing an N-substituted (meth)acrylic amide without need of heat treatment for decomposing a Michael adduct by-produced in an amidation reaction of an ester nor protection-deprotection treatment of a double bond and to provide a method for producing an N-substituted (meth)acrylic amide-containing polymer.SOLUTION: The method for producing an N-substituted (meth)acrylic amide includes reacting a (meth)acrylic acid ester represented by Formula (1) with an amine represented by Formula (2) in the presence of a catalyst while maintaining a temperature of a reaction mixture at 50°C or lower to produce an N-substituted (meth)acrylic amide represented by Formula (3). Formula (1): CH=CRCOOR(R is a hydrogen atom or a methyl group; and Ris a lower alkyl group; Formula (2): R-NH-R(Rand Rare each independently a hydrogen atom, an alkyl group or an alkyl group having a substituent); and Formula (3):CH=CRCON(R)-R(R is the same as that in Formula (1); and Rand Rare the same as those in Formula (2))SELECTED DRAWING: None
申请公布号 JP2016074620(A) 申请公布日期 2016.05.12
申请号 JP20140205261 申请日期 2014.10.03
申请人 AT SILICA CO LTD 发明人 FUKUI KOICHI
分类号 C07C231/02;C07C233/20;C08F8/32 主分类号 C07C231/02
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