PRODUCTION METHOD FOR OLEFIN, AND DEHYDRATION CATALYST EMPLOYED IN SAME

摘要

An object of the present invention is to provide a method of producing a corresponding olefin such as propylene with a high activity and a high selectivity even in a high LHSV range by an intramolecular dehydration reaction of an alcohol such as isopropyl alcohol. The present invention provides a method of producing an olefin represented by General Formula (II) below from an alcohol represented by General Formula (I) below, which method uses, as a dehydration catalyst, a chemically treated silica gel (X) in which an aluminum compound is supported onto a silica gel (A) with an average fine pore diameter of 10 to 50 nm in the amount of 1,000 to 10,000 ppm by weight in terms of aluminum element. (In General Formulae (I) and (II), R1 is selected from alkyl groups of 1 to 5 carbon atoms and R2 is selected from a hydrogen atom and alkyl groups of 1 to 5 carbon atoms.);

主权项

1. An olefin production method, comprising producing an olefin represented by General Formula (II) below from an alcohol represented by General Formula (I) below using, as a dehydration catalyst, a chemically treated silica gel (X) in which an aluminum compound is supported onto a silica gel (A) with an average fine pore diameter of 10 to 50 nm in an amount of 1,000 to 10,000 ppm by weight in terms of aluminum element: (in General Formulae (I) and (II), R1 is selected from alkyl groups of 1 to 5 carbon atoms and R2 is selected from a hydrogen atom and alkyl groups of 1 to 5 carbon atoms).