| 摘要 |
FIELD: chemistry.SUBSTANCE: invention relates to a method of producing porous coordination polymer NH-MIL-101(Al) and to porous coordination polymer NH-MIL-101(Al), obtained using said method. Method involves mixing aluminium salt formula AlCl×6HO and an organic acid 2-amino-1,4-benzene dicarboxylic acid in the presence of a solvent-mixture of water and a polar organic solvent, taken in weight ratio of 1:1-5, respectively. Then the obtained reaction mixture is heated at atmospheric pressure and temperature of 120-130°C under the effect of microwave radiation power up to 200 Watt. Polar organic solvent used is a solvent with boiling temperature higher than 130°C for effective heating of microwave radiation conditions, for example, dimethylsulfoxide, N,N′-dimethylformamide.EFFECT: significant increase of the target product yield, reduced time of the process, elimination of autogenous pressure and obtaining pure product with predominance in its porous structure of mesopores with higher degree of crystallinity and phase purity, which can be used in designing new class of carriers for catalysts fine organic synthesis, as well as in the area of gas separation.3 cl, 3 dwg, 1 tbl, 6 ex |
