发明名称 PROCESS FOR THE ISOMERISATION OF AN EXO DOUBLE BOND
摘要 The present invention concerns a process for the isomerisation of an exo double bond toward an endo double bond being performed in the presence of a catalyst system comprising palladium (Pd) or platinum (Pt) and molecular hydrogen or a hydrogen source.
申请公布号 US2016060200(A1) 申请公布日期 2016.03.03
申请号 US201414768222 申请日期 2014.02.07
申请人 FIRMENICH SA 发明人 BOSHRA Ramez;VANHESSCHE Koenraad;ALEXANDER Anatoly
分类号 C07C45/67 主分类号 C07C45/67
代理机构 代理人
主权项 1. A process for the preparation of a compound of formula (I) wherein R, R1 and R2, simultaneously or independently, represent a hydrogen atom or a linear or branched C1-5 alkyl group; R3 represents a linear or branched C1-5 alkyl or alkenyl group; or R1 and R3, taken together, represent a C2-9 alkanediyl or alkenediyl group optionally substituted by one to two linear or branched C1-5 alkyl groups;by the isomerisation of the corresponding compound of the formula (II) wherein R, R1, R2 and R3 have the same meaning as in formula (I);said isomerisation being performed in the presence of a catalyst system comprisingi) metal selected amongst palladium (Pd) or platinum (Pt);ii) molecular hydrogen or a hydrogen source.
地址 Geneva 8 CH