发明名称 Quinoline-benzoxazole derived compounds for electronic films and devices
摘要 The invention provides a composition comprising at least one compound selected from the following Formulas A, B1, B2, B3, B4 or C:; or a combination thereof (C). For each formula, the R groups are described herein.
申请公布号 US9246108(B2) 申请公布日期 2016.01.26
申请号 US201313828470 申请日期 2013.03.14
申请人 Dow Global Technologies LLC 发明人 Ober Matthias S.;Froese Robert D.
分类号 H01B1/12;H01L51/00;C09K11/06;C07D413/14;C07D413/04;H01L51/50 主分类号 H01B1/12
代理机构 代理人
主权项 1. A composition comprising at least one compound selected from the following Formulas A, B1, B2, B3, B4 or C:A)wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are each, independently, selected from the following: a) hydrogen atom; b) a deuterium atom; c) a (C1-C30) alkyl group; d) a substituted (C1-C30) alkyl group; e) a (C6-C50) aryl group; f) a substituted (C6-C50) aryl group; g) a (C3-C50) heteroaryl group; h) a substituted (C3-C50) heteroaryl group; i) a (C3-C30) cycloalkyl group; j) a substituted (C3-C30) cycloalkyl group; or k) a group represented by —(Ar1)m—(Ar2), wherein Ar1 is selected from the group consisting of the following: a substituted or unsubstituted (C5-C30) arylene group, and a substituted or unsubstituted (C5-C30) heteroarylene group, and Ar2 is selected from the group consisting of the following: a substituted or unsubstituted (C5-C30) aryl group, a substituted or unsubstituted (C5-C30) aryloxy group, and a substituted or unsubstituted (C4-C30) heteroaryl group m is an integer from 0 to 5, and —(Ar1)m— groups in —(Ar1)m—(Ar2) are identical or different from one another; and with the proviso that at least one of R1, R2, R3, and R4 comprises at least 10 carbon atoms and one cyclic aromatic ring; and wherein, optionally, two or more R groups selected from R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 may form one or more ring structures;and with the proviso that none of R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 comprise a hydroxyl, nitrile, isonitrile, sulfone, sulfonamide, primary amine, secondary amine, quaternary ammonium, amide, thioamide, halogen, a bicyclic moiety containing sulfur, thiazolidinedione, thioxothiazolidinone, or a benzoxazole moiety; B1) wherein R2, R3, R4, R5, R6, R7, R8, R9, R10, R2a, R3a, R4a, R5a, R6a, R7a, R8a, R9a, and R10a are each, independently, selected from the following: a) a hydrogen atom, b) a deuterium atom, c) a (C1-C30) alkyl group, d) a substituted (C1-C30) alkyl group, e) a (C6-C50) aryl group, f) a substituted (C6-C50) aryl group, g) a (C3-C50) heteroaryl group, h) a substituted (C3-C50) heteroaryl group, i) a (C3-C30) cycloalkyl group, or j) a substituted (C3-C30) cycloalkyl group; and wherein, optionally, two or more R groups selected from R2, R3, R4, R5, R6, R7, R8, R9 and R10 may form one or more ring structures; and wherein, optionally, two or more R groups selected from R2a, R3a, R4a, R5a, R6a, R7a, R8a, R9a and R10a may form one or more ring structures; and with the proviso that none of R2, R3, R4, R5, R6, R7, R8, R9, R10, R2a, R3a, R4a, R5a, R6a, R7a, R8a, R9a, and R10a comprise an OH, nitrile, isonitrile, sulfone, sulfonamide, primary amine, secondary amine, quaternary ammonium, amide, thioamide, halogen, a bicyclic moiety containing sulfur, thiazolidinedione, thioxothiazolidinone, or a benzoxazole moiety; and wherein L is a linking group comprising at least one carbon atom; B2) wherein R1, R3, R4, R5, R6, R7, R8, R9, R10, R1a, R3a, R4a, R5a, R6a, R7a, R8a, R9a, and R10a are each, independently, selected from the following: a) a hydrogen atom, b) a deuterium atom, c) a (C1-C30) alkyl group, d) a substituted (C1-C30) alkyl group, e) a (C6-C50) aryl group, f) a substituted (C6-C50) aryl group, g) a (C3-C50) heteroaryl group, h) a substituted (C3-C50) heteroaryl group, i) a (C3-C30) cycloalkyl group, or j) a substituted (C3-C30) cycloalkyl group; and wherein, optionally, two or more R groups selected from R1, R3, R4, R5, R6, R7, R8, R9 and R10 may form one or more ring structures; and wherein, optionally, two or more R groups selected from R1a, R3a, R4a, R5a, R6a, R7a, R8a, R9a and R10a may form one or more ring structures; and with the proviso that none of R1, R3, R4, R5, R6, R7, R8, R9, R10, R1a, R3a, R4a, R5a, R6a, R7a, R8a, R9a, and R10a comprise an OH, nitrile, isonitrile, sulfone, sulfonamide, primary amine, secondary amine, quaternary ammonium, amide, thioamide, halogen, a bicyclic moiety containing sulfur, thiazolidinedione, thioxothiazolidinone, or a benzoxazole moiety; and wherein L is a linking group comprising at least one carbon atom;B3) wherein R1, R2, R4, R5, R6, R7, R8, R9, R10, R1a, R2a, R4a, R5a, R6a, R7a, R8a, R9a, and R10a are each, independently, selected from the following: a) a hydrogen atom, b) a deuterium atom, c) a (C1-C30) alkyl group, d) a substituted (C1-C30) alkyl group, e) a (C6-C50) aryl group, f) a substituted (C6-C50) aryl group, g) a (C3-C50) heteroaryl group, h) a substituted (C3-C50) heteroaryl group, i) a (C3-C30) cycloalkyl group, or j) a substituted (C3-C30) cycloalkyl group; and wherein, optionally, two or more R groups selected from R1, R2, R4, R5, R6, R7, R8, R9 and R10 may form one or more ring structures; and wherein, optionally, two or more R groups selected from R1a, R2a, R4a, R5a, R6a, R7a, R8a, R9a and R10a may form one or more ring structures; and with the proviso that none of R1, R2, R4, R5, R6, R7, R8, R9, R10, R1a, R2a, R4a, R5a, R6a, R7a, R8a, R9a, and R10a comprise an OH, nitrile, isonitrile, sulfone, sulfonamide, primary amine, secondary amine, quaternary ammonium, amide, thioamide, halogen, a bicyclic moiety containing sulfur, thiazolidinedione, thioxothiazolidinone, or a benzoxazole moiety; and wherein L is a linking group comprising at least one carbon atom;B4) wherein R1, R2, R3, R5, R6, R7, R8, R9, R10, R1a, R2a, R3a, R5a, R6a, R7a, R8a, R9a, and R10a are each, independently, selected from the following: a) a hydrogen atom, b) a deuterium atom, c) a (C1-C30) alkyl group, d) a substituted (C1-C30) alkyl group, e) a (C6-C50) aryl group, f) a substituted (C6-C50) aryl group, g) a (C3-C50) heteroaryl group, h) a substituted (C3-C50) heteroaryl group, i) a (C3-C30) cycloalkyl group, or j) a substituted (C3-C30) cycloalkyl group; and wherein, optionally, two or more R groups selected from R1, R2, R3, R5, R6, R7, R8, R9 and R10 may form one or more ring structures; and wherein, optionally, two or more R groups selected from Ra1, R2a, R3a, R5a, R6a, R7a, R8a, R9a and R10a may form one or more ring structures; and with the proviso that none of R1, R2, R3, R5, R6, R7, R8, R9, R10, R1a, R2a, R3a, R5a, R6a, R7a, R8a, R9a, and R10a comprise an OH, nitrile, isonitrile, sulfone, sulfonamide, primary amine, secondary amine, quaternary ammonium, amide, thioamide, halogen, a bicyclic moiety containing sulfur, thiazolidinedione, thioxothiazolidinone, or a benzoxazole moiety; and wherein L is a linking group comprising at least one carbon atom; orC) a combination thereof.
地址 Midland MI US