发明名称 FUNGICIDAL 3--OXADIAZOLONE DERIVATIVES
摘要 The present invention provides 3-{heterocyclyl[(heterocyclylmethoxy)imino]methyl}-oxadiazolinone derivatives of formula (I);;wherein A, T and X1 to X3 represent various substituents.
申请公布号 US2016002217(A1) 申请公布日期 2016.01.07
申请号 US201414770098 申请日期 2014.03.03
申请人 BAYER CROPSCIENCE AG 发明人 REBSTOCK Anne-Sophie;DUBOST Christophe;COQUERON Pierre-Yves;MAECHLING Simon;LACHAISE Helene;RINOLFI Philippe;WACHENDORFF-NEUMANN Ulrike
分类号 C07D417/14;A01N43/82;C07D413/14 主分类号 C07D417/14
代理机构 代理人
主权项 1. A compound of formula (I) wherein X1 represents a hydrogen atom, a formyl group, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, a substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, or substituted or non-substituted C1-C8-alkylcarbonyl;X2 and X3 independently represent O or C═O, provided that X2 represents O when X3 is C═O and X2 represents C═O when X3 is OA is selected from the group consisting of A1 to A27: wherein Z1 represents a hydrogen atom, a halogen atom, a nitro group, an amino group, an hydroxyamino group, a carboxylic acid, a hydroxy group, a cyano group, a sulfenyl group, a formyl group, a substituted or non-substituted carbaldehyde O—(C1-C8-alkyl)oxime, a formyloxy group, a carbamoyl group, a N-hydroxycarbamoyl group, sulfenylthioylamino, a pentafluoro-λ6-sulfenyl group, substituted or non-substituted C1-C8-alkoxyamino group, substituted or non-substituted N—C1-C8-alkyl-(C1-C8-alkoxy)-amino group, substituted or non-substituted (C1-C8-alkylamino)-amino group, substituted or non-substituted N—C1-C8-alkyl-(C1-C8-alkylamino)-amino group, a substituted or non-substituted (hydroxyimino)-C1-C6-alkyl group, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted aryl-C2-C8-alkynyl, substituted or non-substituted C3-C8-cycloalkyl-C2-C8-alkynyl, substituted or non-substituted C1-C8-alkoxy, substituted or non-substituted C2-C8-alkenyloxy, substituted or non-substituted C3-C8-alkynyloxy, substituted or non-substituted C1-C8-alkylcarbonyl, substituted or non-substituted N—(C1-C8-alkoxy)-C1-C8-alkanimidoyl, substituted or non-substituted N—C1-C8-alkyl-carbamoyl, substituted or non-substituted N,N′-di-C1-C8-alkyl-carbamoyl, substituted or non-substituted N—C1-C8-alkyloxycarbamoyl, substituted or non-substituted C1-C8-alkoxycarbamoyl, substituted or non-substituted N—C1-C8-alkyl-C1-C8-alkoxycarbamoyl, substituted or non-substituted C1-C8-alkoxycarbonyl, substituted or non-substituted C1-C8-alkylcarbonyloxy, substituted or non-substituted N—C1-C8-alkylaminocarbonyloxy, substituted or non-substituted N,N′-di-C1-C8-alkylaminocarbonyloxy, substituted or non-substituted N—C1-C8-alkylcarbamothioyl, substituted or non-substituted N,N′-di-C1-C8-alkylcarbamothioyl, substituted or non-substituted N—C1-C8-alkyloxycarbamothioyl, substituted or non-substituted C1-C8-alkoxycarbamothioyl, substituted or non-substituted N—C1-C8-alkyl-C1-C8-alkoxycarbamothioyl, substituted or non-substituted (C1-C8-alkyl-carbamothioyl)-oxy, substituted or non-substituted substituted or non-substituted (di-C1-C8-alkyl-carbamothioyl)-oxy, substituted or non-substituted C1-C8-alkylsulfenyl, substituted or non-substituted C1-C8-halogenoalkylsulfenyl having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylsulfinyl, substituted or non-substituted C1-C8-alkylsulfonyl, substituted or non-substituted C1-C8-alkylaminosulfamoyl, substituted or non-substituted (C1-C6-alkoxyimino)-C1-C6-alkyl, substituted or non-substituted (C2-C6-alkenyloxyimino)-C1-C6-alkyl, substituted or non-substituted (C2-C6-alkynyloxyimino)-C1-C6-alkyl, substituted or non-substituted (benzyloxyimino)-C1-C6-alkyl, substituted or non-substituted phenoxy, substituted or non-substituted phenylsulfenyl, substituted or non-substituted aryl, substituted or non-substituted tri(C1-C8-alkyl)-silyloxy, substituted or non-substituted C1-C8-alkylsulfenylamino, substituted or non-substituted C1-C8-alkylsulfonylamino, substituted or non-substituted C1-C8-alkoxysulfonylamino, substituted or non-substituted tri(C1-C8-alkyl)-silyl, substituted or non-substituted (C1-C6-alkylideneamino)oxy, substituted or non-substituted (C2-C6-alkenylideneamino)oxy, substituted or non-substituted (C2-C6-alkynylideneamino)oxy, substituted or non-substituted (benzylideneamino)oxy, substituted or non-substituted (N-hydroxy-C1-C6-alkanimidoyl)amino, substituted or non-substituted (N—C1-C6-alkoxy-C1-C6-alkanimidoyl)amino, substituted or non-substituted C1-C8-alkylamino, substituted or non-substituted C3-C10-cycloalkylamino, substituted or non-substituted C3-C10-cycloalkenylamino, substituted or non-substituted C5-C12-fused bicycloalkylamino, substituted or non-substituted C5-C12-fused bicycloalkenylamino, substituted or non-substituted di-C1-C8-alkylamino, substituted or non-substituted phenylamino, substituted or non-substituted heterocyclylamino, substituted or non-substituted C3-C10-cycloalkyl-C1-C8-alkylamino, substituted or non-substituted aryl-C1-C8-alkylamino, substituted or non-substituted C1-C8-alkoxy-C1-C8-alkylamino, or a group of formula QC(═U)NRa— wherein Q represents a hydrogen atom, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, a substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C3-C8-cycloalkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted C1-C8-alkoxy, substituted or non-substituted C2-C8-alkenyloxy, substituted or non-substituted C2-C8-alkynyloxy, substituted or non-substituted C1-C8-alkylamino, substituted or non-substituted C1-C8-alkylsulfenyl, substituted or non-substituted C2-C8-alkenylsulfenyl, substituted or non-substituted C2-C8-alkynylsulfenyl, substituted or non-substituted arylsulfenyl, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted C5-C12-fused bicycloalkyl, substituted or non-substituted C5-C12-fused bicycloalkenyl, substituted or non-substituted C5-C12-benzofused carbocyclyl, substituted or non-substituted C5-C12-benzofused heterocyclyl, substituted or non-substituted cycloalkoxy; substituted or non-substituted cycloalkenyloxy, substituted or non-substituted aryloxy; substituted or non-substituted heterocyclyloxy, substituted or non-substituted C5-C12-fused bicycloalkoxy, substituted or non-substituted C5-C12-fused bicycloalkenyloxy, substituted or non-substituted C5-C12-benzofused carbocyclyloxy, substituted or non-substituted C5-C12-benzofused heterocyclyloxy, substituted or non-substituted C3-C8-cycloalkyl-C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl-C1-C8-alkoxy, substituted or non-substituted C3-C8-cycloalkoxy-C1-C8-alkyl, substituted or non-substituted heterocyclyl-C1-C8-alkyl, substituted or non-substituted aryl-C1-C8-alkyl, substituted or non-substituted aryl-C1-C8-alkoxy, substituted or non-substituted aryloxy-C1-C8-alkyl, substituted or non-substituted C1-C8-alkoxy-C1-C8-alkyl, substituted or non-substituted C1-C8-alkoxy-C1-C8-alkoxy, substituted or non-substituted aryloxy-C1-C8-alkoxy, substituted or non-substituted C1-C8-alkoxyaryloxy, substituted or non-substituted C1-C8-alkoxy-C1-C8-alkyl, substituted or non-substituted aryl-C2-C8-alkynyloxy, substituted or non-substituted C1-C8-alkylaryl, substituted or non-substituted C1-C8-alkoxyaryl, substituted or non-substituted C1-C8-alkoxy-C1-C8-alkoxy, substituted or non-substituted C1-C8-alkyl-C3-C8-cycloalkoxy, or substituted or non-substituted C1-C8-alkyl-C3-C8-cycloalkyl;U represents a oxygen atom or a sulfur atom;Ra represents a hydrogen atom, a hydroxy group, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, a substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted C1-C8-alkoxy, substituted or non-substituted C3-C10-cycloalkenyl, substituted or non-substituted C5-C12-fused bicycloalkyl, substituted or non-substituted C5-C12-fused bicycloalkenyl, substituted or non-substituted aryl, or substituted or non-substituted heterocyclyl, substituted or non-substituted C1-C8-alkylcarbonyl, substituted or non-substituted aryloxycarbonyl, or substituted or non-substituted C1-C8-alkoxycarbony;Z2, Z3 and Z4 independently represent a hydrogen atom, a halogen atom, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, or substituted or non-substituted C1-C8-alkoxy;K1 represents a hydrogen atom, a formyl group, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, or substituted or non-substituted C1-C8-alkylcarbonyl; T is selected from the group consisting of T1 to T19: Y1 to Y4 independently represent a hydrogen atom, a halogen atom, a nitro group, a cyano group, a substituted or non-substituted carbaldehyde O—(C1-C8-alkyl)oxime, a pentafluoro-λ6-sulfenyl group, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, substituted or non-substituted C1-C8-halogenoalkyl having 1 to 5 halogen atoms, a C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted C1-C8-alkoxy, substituted or non-substituted C1-C8-halogenoalkoxy having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylsulfenyl, substituted or non-substituted C2-C8-alkenyloxy, substituted or non-substituted C3-C8-alkynyloxy, substituted or non-substituted N—(C1-C8-alkoxy)-C1-C8-alkanimidoyl, substituted or non-substituted N—(C1-C8-alkoxy)-C1-C8-halogenoalkanimidoyl having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkoxycarbonyl, substituted or non-substituted C1-C8-alkylcarbonyloxy, substituted or non-substituted C1-C8-alkylsulfinyl, substituted or non-substituted C1-C8-alkylsulfonyl, substituted or non-substituted phenoxy, substituted or non-substituted phenylsulfenyl, substituted or non-substituted aryl, substituted or non-substituted tri(C1-C8-alkyl)-silyloxy, substituted or non-substituted tri(C1-C8-alkyl)-silyl, substituted or non-substituted heterocyclyl, or substituted or non-substituted heterocyclyloxy; and/or a salt, N-oxide, metallic complex and/or metalloidic complex thereof and/or (E) and/or (Z) isomer thereof and/or a mixture thereof.
地址 Monheim DE