发明名称 |
Process for removing oxygenate from an olefin stream |
摘要 |
The present invention relates to a process for producing an olefinic product, comprising (a) preparing a reaction product by converting an oxygenate-comprising feedstock in an oxygenate to olefin process, the reaction product comprising at least C2+ olefins and DME, (b) separating at least part of the reaction product by means of extractive distillation using a butanol solvent into: (i) a first fraction comprising C3− olefins and butanol; and (ii) a second fraction comprising C4+ olefins, DME and butanol; (c) separating the first fraction into: (iii)a C3− olefinic product; and (iv) a third fraction comprising butanol; (d) separating the second fraction into: (v) a DME-comprising C4-C5 olefinic product; and (vi) a fourth fraction comprising butanol and C6+ olefins, wherein at least part of the third and/or fourth fraction are recycled to step (b) together with or as part of the butanol solvent. |
申请公布号 |
US9115103(B2) |
申请公布日期 |
2015.08.25 |
申请号 |
US201314136222 |
申请日期 |
2013.12.20 |
申请人 |
Shell Oil Company |
发明人 |
Van Westrenen Jeroen |
分类号 |
C07C1/00;C07D301/02;C07C7/08;C07C41/42;C07C1/20 |
主分类号 |
C07C1/00 |
代理机构 |
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代理人 |
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主权项 |
1. A process for producing an olefinic product, comprising:
a) preparing a reaction product by converting an oxygenate-comprising feedstock in an oxygenate to olefin process, the reaction product comprising at least C2+ olefins and dimethylether (DME); b) separating at least part of the reaction product by means of extractive distillation using a butanol solvent into:
a first fraction comprising C3− olefins and butanol; anda second fraction comprising C4+ olefins, dimethylether and butanol; c) separating the first fraction into:
a C3− olefinic product; anda third fraction comprising butanol; and d) separating the second fraction into:
a dimethylether-comprising C4-C5olefinic product; anda fourth fraction comprising butanol and C6+ lefins, wherein at least part of the third and/or fourth fraction are recycled to step (b) together with or as part of the butanol solvent. |
地址 |
Houston TX US |