主权项 |
1. A liquid crystal display device comprising:
a pair of substrates, at least one of which is transparent; a liquid crystal layer disposed between the pair of substrates; a group of electrodes formed on at least one of the pair of substrates to apply an electric field to the liquid crystal layer; plural active elements connected to the group of electrodes; and a photo sensitive orientation control film for liquid crystal disposed on at least one of the pair of substrates; wherein said photo sensitive orientation control film is made of a polyimide, a first compound, and a second compound; wherein the first compound contains a polymer unit given by the following formula (102), (103), (113), (114), (116), or (117); wherein the second compound contains a polymer unit given by the following formula (102), (103), (113), (114), (116), (117), (121), or (122) wherein the cyclobutane section is replaced with a section given by at least one of the following formulae (51) through (55): wherein each R1 is individually hydrogen or an alkyl group containing 1 to 8 carbon atoms, each R2 is individually a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a phenyl group, an alkyl group containing 1 to 6 carbon atoms, an alkoxy group containing 1 to 6 carbon atoms, a vinyl group (—(CH2)m-CH═CH2, m=0, 1, 2), or an alkynyl group (—(CH2)m-C≡CH, m=0, 1, 2), and Ar is an aromatic compound; wherein each R1 is individually hydrogen or an alkyl group containing 1 to 8 carbon atoms, each R2 is individually a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a phenyl group, an alkyl group containing 1 to 6 carbon atoms, an alkoxy group containing 1 to 6 carbon atoms, a vinyl group (—(CH2)m-CH═CH2, m=0, 1, 2), or an alkynyl group (—(CH2)m-C≡CH, m=0, 1, 2), and Ar is an aromatic compound; wherein each R1 is individually an alkyl group containing 1 to 8 carbon atoms, each R2 is individually a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a phenyl group, an alkyl group containing 1 to 6 carbon atoms, an alkoxy group containing 1 to 6 carbon atoms, a vinyl group (—(CH2)m-CH═CH2, m=0, 1, 2), or an alkynyl group (—(CH2)m-C≡CH, m=0, 1, 2), and Ar is an aromatic compound; wherein each R2 is individually a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a phenyl group, an alkyl group containing 1 to 6 carbon atoms, an alkoxy group containing 1 to 6 carbon atoms, a vinyl group (—(CH2)m-CH═CH2, m=0, 1, 2), or an alkynyl group (—(CH2)m-C≡CH, m=0, 1, 2), and Ar is an aromatic compound; wherein: each hydrogen atom of the aromatic rings individually may instead be a fluorine atom, a chlorine atom, a bromine atom, a phenyl group, an alkyl group containing 1 to 8 carbon atoms, an alkoxy group, a vinyl group, or an alkynyl group; and Z is any of the following functional groups, (—CH2—, —CO2—, —NH—, —O—, —S—, —SO—, —SO2—), wherein each hydrogen atom may instead be a fluorine atom, a chlorine atom, a bromine atom, a phenyl group, an alkyl group containing 1 to 8 carbon atoms, an alkoxy group, a vinyl group or an alkynyl group. |