| 摘要 |
<p><P>PROBLEM TO BE SOLVED: To provide a method for producing allyl compounds by dehydrative allylation of allyl alcohols and the like in the presence of a catalyst system consisting of a catalyst precursor and a ligand. <P>SOLUTION: In the method for producing allyl compounds: the catalyst precursor consisting of a complex compound having a ruthenium atom is mixed with an (S, S) or (R, R) type ligand having a specific structure; and then, the allyl alcohols and a substrate are mixed to be reacted with each other. In the allyl alcohols: a carbon atom and a hydrogen atom are connected to a carbon atom in the third position or a carbon atom is connected to a carbon atom in the first position; and these carbon atoms are sp<SP POS="POST">2</SP>or sp hybridized carbon atoms or these carbon atoms are connected to carbon atoms only. The substrate is a cyclic compound having carbonyl groups in the first and third positions and having a carbon atom in the second position wherein the carbon atom is connected to a carbon atom or a hydrogen atom. <P>COPYRIGHT: (C)2013,JPO&INPIT</p> |
