Insecticidal pyrrolidin-yl-aryl-carboxamides

摘要

The invention relates to compounds of formula (I): where A1, A2, A3, A4, G1, R1, R2, R3 and R4 are as defined in claim 1; or a salt or N-oxide thereof. Furthermore, the present invention relates to processes and intermediates for preparing compounds of formula (I), to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising the compounds of formula (I) and to methods of using the compounds of formula (I) to control insect, acarine, nematode and mollusc pests.;

主权项

1. A compound of formula (I) where A1, A2, A3 and A4 are independently of each other C—H, C—R5 or nitrogen; G1 is oxygen or sulfur; R1 is hydrogen, C1-C8alkyl, C1-C8alkoxy-, C1-C8alkylcarbonyl-, C1-C8alkoxycarbonyl- or C1-C8haloalkoxycarbonyl-; R2 is a group of formula (II) where L is a single bond or C1-C6alkylene; and Y1, Y2 and Y3 are independently of another CR8R9, C═O, C═N—OR10, N—R10, S, SO, SO2, S═N—R10or SO═N—R10, provided that at least one of Y1, Y2 or Y3 is not CR8R9, C═O or C═N—OR10; R3 is C1-C8haloalkyl; R4 is aryl or aryl substituted by one to five R7, or heteroaryl or heteroaryl substituted by one to five R7; each R5 is independently halogen, cyano, nitro, C1-C8alkyl, C1-C8haloalkyl, C2-C8alkenyl, C2-C8haloalkenyl, C2-C8alkynyl, C2-C8haloalkynyl, C3-C10cycloalkyl, C1-C8alkoxy-, C1-C8haloalkoxy-, C1-C8alkylthio-, C1-C8haloalkylthio-, C1-C8alkylsulfinyl-, C1-C8haloalkyl-sulfinyl-, C1-C8alkylsulfonyl- or C1-C8haloalkylsulfonyl-, or two R5 on adjacent carbon atoms together form a —CH═CH—CH═CH— bridge; R6 is hydrogen, C1-C8haloalkyl or C1-C8alkyl; each R7 is independently halogen, cyano, nitro, C1-C8alkyl, C1-C8haloalkyl, C2-C8alkenyl, C2-C8haloalkenyl, C2-C8alkynyl, C2-C8haloalkynyl, hydroxy, C1-C8alkoxy-, C1-C8haloalkoxy-, mercapto, C1-C8alkylthio-, C1-C8haloalkylthio-, C1-C8alkylsulfinyl-, C1-C8haloalkylsulfinyl-, C1-C8alkylsulfonyl-, C1-C8haloalkylsulfonyl-, C1-C8alkylcarbonyl-, C1-C8alkoxycarbonyl-, aryl or aryl substituted by one to five R11, or heterocyclyl or heterocyclyl substituted by one to five R11; each R8 and R9 is independently hydrogen, halogen, C1-C8alkyl or C1-C8haloalkyl; each R10 is independently hydrogen, cyano, C1-C8alkyl, C1-C8haloalkyl, C1-C8alkylcarbonyl-, C1-C8haloalkylcarbonyl-, C1-C8alkoxycarbonyl-, C1-C8haloalkoxycarbonyl-, C1-C8alkylsulfonyl-, C1-C8haloalkylsulfonyl-, aryl-C1-C4alkylene- or aryl-C1-C4alkylene- where the aryl moiety is substituted by one to three R12, or heteroaryl-C1-C4alkylene- or heteroaryl-C1-C4alkylene- where the heteroaryl moiety is substituted by one to three R12; each R11 and R12 is independently halogen, cyano, nitro, C1-C8alkyl, C1-C8haloalkyl, C1-C8alkoxy-, C1-C8haloalkoxy- or C1-C8alkoxycarbonyl-; or a salt or N-oxide thereof.