发明名称 |
Production of tetrahydrofuran-2, 5-dimethanol from isosorbide |
摘要 |
Disclosed herein are processes comprising contacting isosorbide with hydrogen in the presence of a first hydrogenation catalyst to form a first product mixture comprising tetrahydrofuran-2,5-dimethanol. The processes can further comprise heating the first product mixture in the presence of hydrogen and a second hydrogenation catalyst to form a second product mixture comprising 1,6-hexanediol. The first and second hydrogenation catalysts can be the same or different. |
申请公布号 |
US8884035(B2) |
申请公布日期 |
2014.11.11 |
申请号 |
US201213729401 |
申请日期 |
2012.12.28 |
申请人 |
E I du Pont de Nemours and Company |
发明人 |
de Silva Wathudura Indika Namal;Korovessi Ekaterini;Menning Carl Andrew;Murphy Joseph E;Ritter Joachim C;Sengupta Sourav Kumar;Stauffer Christina S |
分类号 |
C07D307/04;C07D307/12 |
主分类号 |
C07D307/04 |
代理机构 |
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代理人 |
|
主权项 |
1. A process comprising:
a) contacting isosorbide with hydrogen in the presence of a first hydrogenation catalyst at a first temperature between about 150° C. and about 400° C. and at a first pressure between about 500 psi to about 5000 psi to form a first product mixture comprising tetrahydrofuran-2,5-dimethanol. |
地址 |
Wilmington DE US |